Ventilate a tune (3)
I believe the answer is:
air
I believe this clue is a double definition.
'ventilate' is the first definition.
(synonyms)
'a tune' is the second definition.
('air' can be a synonym of 'tune')
(Other definitions for air that I've seen before include "Ventilate or give expression to" , "Atmosphere; appearance" , "Gas mixture required for breathing" , "Bearing, manner" , "Simple tune" .)