Very musical class council got rid of - first-rate (5)
I believe the answer is:
assai
'very musical' is the definition.
(musical term for 'very')
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for assai that I've seen before include "Musician's very" , "Palm tree" , "attack in concert, for the most part" , "Very (in music scores)" , "Produced offspring" .)