Very tiny boat, music playing (9)
I believe the answer is:
subatomic
'very tiny' is the definition.
'boat music playing' is the wordplay.
'playing' is an anagram indicator.
'boat'+'music'='boatmusic'
'boatmusic' anagrammed gives 'SUBATOMIC'.
(Other definitions for subatomic that I've seen before include "Of smaller than elementary particles" , "Like 9 across" , "Smaller than a basic particle of matter" .)