Very well, better it, chum! (9)
I believe the answer is:
capitally
'very well' is the definition.
(I've seen this before)
'better it chum' is the wordplay.
'better' becomes 'cap' (I've seen this before).
'chum' becomes 'ally' (I can't explain this - if you can you should give a lot more credence to this answer).
'cap'+'it'+'ally'='CAPITALLY'
Can you help me to learn more?
(Other definitions for capitally that I've seen before include "Very well" , "Admirably" , "in a fine manner" .)