Want to come over? (6)
I believe the answer is:
defect
'want' is the definition.
(I've seen this before)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for defect that I've seen before include "Flaw - change sides" , "Want or imperfection" , "Desert - flaw" , "To change sides dishonourably" , "Desert and join the other side" .)