Warning chief to dine (5,2)
I believe the answer is:
heads up
'warning' is the definition.
(I know that heads-up is a type of warning)
'chief to dine' is the wordplay.
'chief' becomes 'head' (synonyms).
'to dine' becomes 'sup' (synonyms).
'head'+'sup'='HEADS-UP'
(Other definitions for heads up that I've seen before include "Warning of impending event" , "Word to the wise" , "Alert" .)