Weary, tired (5)
I believe the answer is:
bored
I believe this clue is a double definition.
'weary' is the first definition.
(I've seen this before)
'tired' is the second definition.
('bore' can be a synonym of 'tire')
(Other definitions for bored that I've seen before include "Wearied by tedium" , "Weary and impatient" , "Suffering from ennui" , "Drilled (a hole)" , "Brassed off" .)