Well-mannered cops, having time for Charlie (6)
I believe the answer is:
polite
'well-mannered' is the definition.
(similar in meaning)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for polite that I've seen before include "Cultivated" , "(Of society) refined" , "Of courteous manners" , "Well mannered" , "Not rude" .)