When caught, all but the novice snarled! (6)
I believe the answer is:
snared
'when caught' is the definition.
'snared' can be an answer for 'caught' (snaring is a kind of catching). I am unsure of the 'when' bit.
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for snared that I've seen before include "Caught in trap as by poacher" , "Caught in a trap like rabbit in noose" , "Enticed and trapped" , "Entrapped" , "Trapped by sander" .)