Who'd act barking? Guard, primarily (8)
I believe the answer is:
watchdog
'who'd act barking? guard primarily' is the definition.
I can't tell whether this definition defines the answer.
'who'd act barking? guard primarily' is the wordplay.
'barking?' indicates anagramming the letters (UK slang for mad).
'primarily' indicates taking the first letters.
The initial letter of 'guard' is 'g'.
'whod'+'act'='whodact'
'whodact' is an anagram of 'watchdo'.
'watchdo'+'g'='WATCHDOG'
Can you help me to learn more?
(Other definitions for watchdog that I've seen before include "TV show" , "Kind of guardian, maybe canine" , "Monitoring organisation" , "protector" , "Animal guarding property - guardian against inefficiency or illegality" .)