Who's in charge of bishops? Big ape, perhaps (7)
I believe the answer is:
primate
I believe this is a double definition.
'who's in charge of bishops?' is the first definition.
'big ape perhaps' is the second definition.
(Other definitions for primate that I've seen before include "Highest-ranking bishop" , "Man (or monkey)" , "Man in the mitre" , "Higher mammal" , "Archbishop - monkey, perhaps" .)