Williams may well be looked up to (5)
I believe the answer is:
venus
'williams' is the definition.
Both the answer and definition are singular nouns.
Maybe there's an association between them I don't understand?
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for venus that I've seen before include "Solar system planet" , "Roman goddess of love" , "Next planet in" , "Morning star" , "Evening star" .)