Wing headed by a 'W' when pronounced? (6)
I believe the answer is:
annexe
'wing' is the definition.
('annexe' can be a synonym of 'wing')
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for annexe that I've seen before include "Additional room etc for house" , "Additional building" , "extra space" , "Attached (set of) room(s)" , "Small building added to another" .)