With no prospect of compensation, totally loveless marriage turned bitter (9)
I believe the answer is:
uninsured
'with no prospect of compensation' is the definition.
(without insurance cover)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for uninsured that I've seen before include "with no policies" , "Not covered against loss" , "Not covered for losses" , "Being without cover" .)