With such a sum, you're not badly off (6)
I believe the answer is:
goodly
'with such a sum you're' is the definition.
I can't tell whether this definition defines the answer.
'not badly off' is the wordplay.
'not badly' becomes 'good' ('good' is the opposite to 'badly').
'off' becomes 'ly' (I can't justify this - if you can you should give a lot more credence to this answer).
'good'+'ly'='GOODLY'
Can you help me to learn more?
(Another definition for goodly that I've seen is " Excellent, virtuous (arch.), considerable (quantity)".)