Without protection, change of emphasis results in accident (6)
I believe the answer is:
mishap
'accident' is the definition.
(I know that accident can be written as mishap)
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for mishap that I've seen before include "An accident or unlucky event" , "Unfortunate minor accident" , "Blow" , "Contretemps" , "An accident, piece of bad luck" .)