A barrier made of pretty stone (5)
I believe the answer is:
agate
'pretty stone' is the definition.
'agate' can be an answer for 'stone' (agate is a type of stone). I'm not sure about the 'pretty' bit.
'a barrier' is the wordplay.
'barrier' becomes 'gate' (gate is a kind of barrier).
'a'+'gate'='AGATE'
'made of' is the link.
Can you help me to learn more?
(Other definitions for agate that I've seen before include "Ornamental form of quartz" , "Quartz with bands of colour, used in jewellery" , "Semi-precious quartz" , "Decorative stone" , "Type of quartz" .)