A collector's book, perhaps (5)
I believe the answer is:
album
'a collector's book' is the definition.
(I've seen this in another clue)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for album that I've seen before include "Book for filling in" , "CD or photo book" , "Photograph/stamp book" , "Book of blank pages for collectables, memorabilia etc." , "Book of collections" .)