A gold one, I'd be possessive about! (4)
I believe the answer is:
mine
'a gold' is the definition.
Although both the answer and definition are singular nouns, I can't see how they can define each other.
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for mine that I've seen before include "Donnybrook" , "Pit; belonging to me" , "Excavate for minerals" , "Pit; source" , "Bomb - colliery" .)