A nation religiously on guard, perhaps (5)
I believe the answer is:
swiss
'a nation' is the definition.
(I know that Swiss is a type of nation)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for swiss that I've seen before include "-- Cheese plant; -- roll" , "Gruyere nationality" , "From Zurich, say?" , "like Federer" , "Sort of roll, of papal Guard" .)