A sunny one can be a bit shady (3)
I believe the answer is:
day
'a sunny one' is the definition.
Although both the answer and definition are singular nouns, I cannot see how one could define the other.
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for day that I've seen before include "Lewis as poet" , "Doris -, US actress" , "24-hour period" , "Born yesterday" , "Dawn to dusk" .)