A united country (4)
I believe the answer is:
peru
'country' is the definition.
(I know that Peru is a country)
'a united' is the wordplay.
'a' becomes 'per' (eg 'one a day' means 'one per day').
'united' becomes 'U' (abbreviation).
'per'+'u'='PERU'
(Other definitions for peru that I've seen before include "Land of the Incas" , "Nazca, Cuzco here" , "Machu Picchu country" , "Homeland of Paddington Bear" , "Lima's country" .)