Actively working (2,4)
'actively working' is the definition.
(I've seen this in another clue)
This is the entire clue.
(Other definitions for on duty that I've seen before include "Working at a particular time" , "As working policemen are" , "What working nurses are" , "Engaged in one's regular work" , "(Of soldier) working" .)
(Other definitions for at the coalface that I've seen before include "like worker of mine?" , "Not deskbound" .)