Actually form a new association (6)
I believe the answer is:
really
'actually' is the definition.
(I know that actually can be written as really)
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for really that I've seen before include "are you sure?" , "Actually, truly" , "Actually, no kidding" , "Do you mean it?" , "Genuinely" .)