Agree to be heir to? (6)
I believe the answer is:
accede
'agree to' is the definition.
(thesaurus)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for accede that I've seen before include "Agree to what is proposed" , "'Take office, as king say (6)'" , "Yield" , "Grant, agree to proposal" , "Agree (to) - come into office" .)