An entrance that may impress in the ring (5)
I believe the answer is:
agate
'may impress in the ring' is the definition.
Although both the answer and definition are singular nouns, I can't see how one could define the other.
'an entrance' is the wordplay.
'an' becomes 'a'.
'entrance' becomes 'gate' (type of entrance).
'a'+'gate'='AGATE'
'that' acts as a link.
Can you help me to learn more?
(Other definitions for agate that I've seen before include "marble" , "Semi-precious stone" , "Ornamental form of quartz" , "Precious stone" , "Variegated chalcedony" .)