As part morning, first extra sugar substitute (9)
I believe the answer is:
aspartame
'sugar substitute' is the definition.
(I've seen this before)
'as part morning first extra' is the wordplay.
'morning' becomes 'am' (as in 12:00 AM).
'first extra' becomes 'e' (1st letter of 'extra').
'as'+'part'+'am'+'e'='ASPARTAME'
(Other definitions for aspartame that I've seen before include "Sugar substitute" , "Strong artificial sweetener -- same apart (anag)" , "What sweetens" .)