Astute waif initially avoided scrap (5)
I believe the answer is:
shred
'scrap' is the definition.
(both can mean a small amount of material)
I can't explain the remainder of the clue.
(Other definitions for shred that I've seen before include "Torn-off fragment" , "Rip up" , "Bit of cloth" , "Strip of material; a very small amount" , "Tatter; small amount" .)