At heart, most important (7)
I believe the answer is:
central
'most important' is the definition.
(I've seen this before)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for central that I've seen before include "Near the middle" , "Extremely important" , "like this answer" , "Most important, principal" , "Key" .)