Atop donkey is Greek millionaire (7)
I believe the answer is:
onassis
'greek millionaire' is the definition.
'atop donkey is' is the wordplay.
'atop' becomes 'on'.
'donkey' becomes 'ass' (ass is a term for a donkey).
'on'+'ass'+'is'='ONASSIS'
(Other definitions for onassis that I've seen before include "big name in shipping" , "Aristotle -, married Jackie Kennedy" , "First lady once" , "Greek businessman" , "Shipowner called Aristotle" .)