Begin to show surprise (5)
I believe the answer is:
start
This clue is a double definition.
'begin' is the first definition.
('start' can be a synonym of 'begin')
'show surprise' is the second definition.
'to' acts as a link.
(Other definitions for start that I've seen before include "Begin with sudden movement of surprise" , "Take the first step" , "Jerk" , "Jump suddenly" , "Commencement" .)