Beheaded it would be even more venomous (4)
I believe the answer is:
wasp
'it would be even more venomous' is the definition.
The definition suggests a singular noun which matches the answer.
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for wasp that I've seen before include "Striped stinger" , "Insect often irritating in summer" , "colonist" , "Insect; thin (waist)" , "Influential American" .)