Best canine, surprisingly, shows ability to resist temptation (10)
I believe the answer is:
abstinence
'ability to resist temptation' is the definition.
I can't judge whether this definition defines the answer.
'best canine surprisingly' is the wordplay.
'surprisingly' is an anagram indicator (a surprising ordering of the letters).
'best'+'canine'='bestcanine'
'bestcanine' is an anagram of 'ABSTINENCE'.
'shows' is the link.
Can you help me to learn more?
(Other definitions for abstinence that I've seen before include "Not drinking" , "Temperance" , "Practice of refraining from indulging an appetite" , "Teetotalism" , "Staying away from" .)