Can they magically charm humour, as out of cash points? (7)
I believe the answer is:
witches
'can they magically charm' is the definition.
The definition suggests an adverb but the answer is not.
'humour as out of cash points?' is the wordplay.
'humour' becomes 'wit' (synonyms).
'out of' indicates named letters should be taken away.
'points?' becomes 'es' (E is an example).
'cash' with 'as' removed is 'ch'.
'wit'+'ch'+'es'='WITCHES'
Can you help me to learn more?
(Other definitions for witches that I've seen before include "Members of a coven" , "Enchantresses" , "Female sorcerers" .)