Catch on to a branch (4)
I believe the answer is:
twig
I believe this is a double definition.
'catch on' is the first definition.
(synonyms)
'branch' is the second definition.
(I know that twig is a more specific form of the action branch)
'to a' acts as a link.
(Other definitions for twig that I've seen before include "Suddenly see; branchlet" , "a small piece of gum?" , "Suddenly realise" , "Small woody shoot" , "Small tree shoot" .)