Catch, then lets slip, which is irritating (7)
I believe the answer is:
nettles
'is irritating' is the definition.
I can't judge whether this defines the answer.
'catch then lets slip' is the wordplay.
'catch' becomes 'net' (net can mean to catch).
'then' is a charade indicator (letters next to each other).
'slip' is an anagram indicator.
'lets' anagrammed gives 'tles'.
'net'+'tles'='NETTLES'
'which' is the link.
Can you help me to learn more?
(Other definitions for nettles that I've seen before include "Plants with stinging hairs" , "One acting Chief Inspector on TV" , "Irritates" .)