Cinders - a girl slaving, initially (5)
I believe the answer is:
ashes
'cinders' is the definition.
(thesaurus)
'a girl slaving initially' is the wordplay.
'girl' becomes 'she' (**).
'initially' indicates taking the first letters.
The first letter of 'slaving' is 's'.
'a'+'she'+'s'='ASHES'
(Other definitions for ashes that I've seen before include "''... to ..., dust to dust'' (burial service)" , "sports contest" , "trees" , "Test cricket series" , "Eng./Aus. cricket trophy" .)