Curious opposites are back-to-back (5)
I believe the answer is:
nosey
'curious' is the definition.
(similar in meaning)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for nosey that I've seen before include "Curious in nasal way" , "Impertinent" , "Prying" , "Showing too much interest in other people's affairs" , "Offensively curious or inquisitive" .)