Deputy capable of some circumlocution (5)
I believe the answer is:
locum
'deputy' is the definition.
(both can mean a substitute or stand-in)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for locum that I've seen before include "Medical temp?" , "Professional who stands in for another" , "Temporary deputy for doctor" , "Professional who substitutes temporarily for another" , "A substitute or stand-in doctor" .)