Discolouration in satin (5)
I believe the answer is:
stain
'discolouration' is the definition.
(synonyms)
'satin' is the wordplay.
'satin' anagrams to 'STAIN'.
Though, I am not sure how the anagram is indicated.
'in' is the link.
Can you help me to learn more?
(Other definitions for stain that I've seen before include "Discolour - blemish" , "Dirty mark; dye" , "Spot - shame" , "Smear" , "Colour, dye" .)