Entrance, captivate (7)
I believe the answer is:
bewitch
I believe this is a double definition.
'entrance' is the first definition.
(I know that entrance can be written as bewitch)
'captivate' is the second definition.
(I know that captivate can be written as bewitch)
(Other definitions for bewitch that I've seen before include "intrigue" , "Get intoxicated" , "Put under a magic spell, or charm" , "add glamour" , "Fascinate - charm" .)