Except for being unique (4)
I believe the answer is:
only
'unique' is the definition.
('only' can be a synonym of 'unique')
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for only that I've seen before include "And nothing more; sole" , "Mere" , "And no one else" , "Exclusive - individual" , "Except that; single" .)