Experience discrimination (5)
I believe the answer is:
taste
I believe this is a double definition.
'experience' is the first definition.
(taste can mean to experience or try out)
'discrimination' is the second definition.
(I know that taste is a type of discrimination)
(Other definitions for taste that I've seen before include "A test (anag)" , "Fine discernment" , "Savour, relish" , "One of the senses" , "Savour in the mouth" .)