First impression that establishes the truth (5)
I believe the answer is:
proof
'first impression' is the definition.
'proof' can be an answer for 'impression' (proof is a kind of impression). I'm unsure of the 'first' bit.
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for proof that I've seen before include "whisky's strength?" , "Specimen" , "Incontrovertible evidence" , "Strength of spirit" , "a writer may check" .)