Flock mistakenly got grain once (12)
I believe the answer is:
congregation
'flock' is the definition.
(thesaurus)
'mistakenly got grain once' is the wordplay.
'mistakenly' indicates anagramming the letters.
'got'+'grain'+'once'='gotgrainonce'
'gotgrainonce' is an anagram of 'CONGREGATION'.
(Other definitions for congregation that I've seen before include "Group assembling for worship" , "Group of worshippers" .)