Fool, possibly, principally serving in arid waste (7)
I believe the answer is:
dessert
'fool possibly' is the definition.
(fool is a type of dessert)
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for dessert that I've seen before include "Sweet, afters" , "End of meal" , "Spotted Dick is one" , "Sweet, last course of a meal" , "tart?" .)