For certain players, cash in advance (4)
I believe the answer is:
ante
'in advance' is the definition.
(thesaurus)
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for ante that I've seen before include "Hoofed mammal" , "Stake, bet" , "expected from stake" , "Initial contribution to the common pot" , "Stake put up by a poker-player before receiving cards" .)