Crossword Genius

Goes off to airport terminal and leaves Palermo - how maddening! (8)

Ross

I believe the answer is:

irritant

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'maddening' is the definition.
Both the answer and definition are adjectives. Maybe there's an association between them I don't understand?

I don't understand the rest of the clue.

Can you help me to learn more?

(Other definitions for irritant that I've seen before include "Source of continual annoyance" , "Annoying factor" , "Something that causes annoyance and bad temper" , "Something that chafes or annoys" , "Trouble" .)

I've seen this clue in The Irish Times.
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