Good little boy, but apt to bite! (4)
I believe the answer is:
gnat
'apt to bite' is the definition.
I can't tell whether this definition defines the answer.
'good little boy' is the wordplay.
'good little' becomes 'g' (abbreviation for good).
'boy' becomes 'nat' ().
'g'+'nat'='GNAT'
'but' is the link.
Can you help me to learn more?
(Other definitions for gnat that I've seen before include "small irritant" , "Insect often hovering over stagnant water" , "Stinging insect" , "Tiny biting insect" , "Small biter" .)