Group in most natural surroundings (7)
I believe the answer is:
element
'surroundings' is the definition.
(element is a kind of surroundings)
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for element that I've seen before include "part of a toaster" , "lead, for example" , "One of the periodic table" , "Chemical building-block" , "briefly identified by Al or Mo, among others" .)